Aggregation-induced enhanced emission (AIEE) molecules, novel luminescent materials with high solid-state emission efficiencies, are important in the applications of optoelectronics, biomedical probes and chemical sensors.
Most aromatic AIEE molecules have complex structures consisting of multiple aromatic rings and/or polycyclic skeletons.
Recently, Prof. QING Guangyan's group from the Dalian Institute of Chemical Physics (DICP) of the Chinese Academy of Sciences (CAS) found that 2-aminophenylboronic acid (2-APBA) with a simple structure was highly emissive in the solid state. They further revealed that 2-APBA exists in a dimeric form, and the 2-APBA dimer is a novel AIEE molecule.
This work was published in Chemical Science on August 18.
The 2-APBA dimer tending to aggregate into a highly ordered structure is AIEE-active (Image by LI Xiaopei)
"We are glad to find that a small and simple molecule, because of the ordered aggregation, could emit extraordinary strong fluorescence with high absolute quantum yield," said Prof. QING.
The researchers applied 2-APBA in sensing CO2 based on its reversible AIEE fluorescence quenching and recovery, and disclosed new kinds of dynamic covalent B-N and B-O bonds. They proposed a strategy to fabricate a CO2-responsive nano-gating system based on the dynamic covalent B-N and B-O bonds.
This work was supported by the National Natural Science Foundation of China, DICP Innovation Funding, and the Liaoning Revitalization Talents Program.
A group led by Prof. WANG Feng from the Dalian Institute of Chemical Physics reviewed the recent advances in the lignin C–C and C–O bond cleavages induced by heteroatoms X (N, Si, I and Li), which also lead to functionalized products containing C–X and O–X bonds.
Recently, a research group led by Prof. ZHANG Yongsheng from the Institute of Solid State Physics, Hefei Institutes of Physical Science successfully explained the novel physical mechanisms behind Pyrite-type ZnSe2.
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